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You have to create your wallets on the titan there you will select the coins you want to keep. From there on the android app you will select connect to cold wallet and it will read the QR codes from the titan this will add the addresses to your app
From there everything is done on the app until you need to sign a transaction then you will use the app and the titan. Whenever you want to add a new coin you reprat the steps from adding on the titan then scanning on the app.
If you need anything just reply here and ill respond as best i can.